| 流场形全固态电极和3D打印流通池测定铁含量 |
| |
| 引用本文： | 贺小云,王济奎,金栋,洪颖,吕丹丹,杨晓露,张建枚,陈国松.流场形全固态电极和3D打印流通池测定铁含量[J].工业水处理,2017,37(3). |
| |
| 作者姓名： | 贺小云 王济奎 金栋 洪颖 吕丹丹 杨晓露 张建枚 陈国松 |
| |
| 作者单位： | 1. 南京工业大学化学与分子工程学院,江苏南京210009;常州亚邦制药有限公司,江苏常州213200;2. 南京工业大学化学与分子工程学院,江苏南京,210009;3. 中国特种设备检测研究院,北京,100029;4. 南京工业大学化学与分子工程学院,江苏南京210009;南京出入境检验检疫局,江苏南京210046;5. 中石化水处理药剂评定中心,北京,102500 |
| |
| 基金项目： | 973国家重点基础研究发展计划资助项目，国家质检总局科研项目 |
| |
| 摘 要： | 首次提出流场形全固态(FFSS)电极的概念,设计并制备了FFSS丝网印刷电极,结合3D打印薄层流通池(TLFC),在流动状态下对邻菲啰啉-二价铁络合物进行循环伏安法(CV)扫描。结果表明,该体系对铁的测量灵敏度高、重现性好,线性范围为0.02~2.0 mg/L,检出限0.006 mg/L,比邻菲啰啉分光光度法更适用于水质的日常监测。该方法成功用于对循环冷却水中总铁的测定,加标回收率为97%~102%。
|
| 关 键 词： | 流场形全固态电极 3D打印薄层流通池 流动循环伏安法 循环冷却水 总铁 |
Determination of iron content by means of flow-field shaped solid electrode and 3D-printed flow cell |
| |
| He Xiaoyun,Wang Jikui,Jin Dong,Hong Ying,L&#; Dandan,Yang Xiaolu,Zhang Jianmei,Chen Guosong.Determination of iron content by means of flow-field shaped solid electrode and 3D-printed flow cell[J].Industrial Water Treatment,2017,37(3). |
| |
| Authors: | He Xiaoyun Wang Jikui Jin Dong Hong Ying L&#; Dandan Yang Xiaolu Zhang Jianmei Chen Guosong |
| |
| Affiliation: | He Xiaoyun,Wang Jikui,Jin Dong,Hong Ying,Lü Dandan,Yang Xiaolu,Zhang Jianmei,Chen Guosong |
| |
| Abstract: | The concept of flow field shaped solid (FFSS) electrode is put forward for the first time.The FFSS screenprinted electrode has been designed and prepared,combining with a 3D-printed thin-layer flow cell (TLFC).Under flow state,the Fe (phen)3] 2+ complex is scanned by cyclic voltammetry (CV).The results show that the developed system shows high measuring sensitivity and good reproducibility for iron.Its linear range is 0.02 to 2.0 mg/L and detection limit is 0.006 mg/L.Compared with Phenanthroline spectrophotometry,it is more suitable for daily monitoring of water quality.This method has successfully been used for the determination of the total iron in circulating cooling water.Its tagged recovery rate is in the range of 97％ to 102％. |
| |
| Keywords: | flow-field shaped solid electrode 3D-printed thin-layer flow cell flow cyclic voltammetry circulating cooling water total iron |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
