Luminescence of Cr-doped ZnGa2O4 thin films deposited by pulsed laser ablation |
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Authors: | Qiang Shi Changzheng Wang Dong ZhangShuhong Li Liming ZhangWenjun Wang Junying Zhang |
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Affiliation: | a School of Physics Science and Information Engineering, Liaocheng University, Shandong 252059, PR Chinab Institute of Nonferrous Metal Research, Liaocheng University, Shandong 252059, PR Chinac Department of Physics, Beihang University, Beijing 100191, PR China |
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Abstract: | Chromium-doped zinc gallate powder is synthesized via a solid-state reaction and subsequently deposited as a thin film on quartz substrates by using a pulsed laser deposition technique under two different deposition conditions. The films are characterized with X-ray diffraction, scanning electron microscopy, UV-vis spectrophotometry and luminescent measurements. As the oxygen pressure is changed from 0 to 1 Pa, we find that the grain size gets smaller, the crystallinity improves, the band-gap energy increases, the excitation peaks of the charge transfer band exhibit a remarkable blue-shift from 263 to 247 nm and the intensity of the red emission (694 nm) is enhanced. The results suggest that the structural and luminescent properties of ZnGa2O4:Cr3 + thin film phosphors are improved by deposition at an oxygen pressure of 1 Pa. |
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Keywords: | Chromium doping Zinc gallium oxide Thin films Luminescence Pulsed laser deposition |
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