A novel plasma-enhanced way for surface-functionalization of polymeric substrates |
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Authors: | S Alvarez-Blanco S Manolache F Denes |
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Affiliation: | (1) Biological Systems Engineering and, US;(2) Center for Plasma-Aided Manufacturing, University of Wisconsin-Madison, Madison WI 53706, USA, US |
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Abstract: | Summary
In this contribution a novel, low-pressure RF-plasma-enhanced approach is suggested for the surface functionalization of polymeric
substrates. The method takes advantage of the high reactivity Ar-plasma generated free radical sites located on PE substrate
surfaces, which can promote under in situ conditions, heterogeneous chemical reactions with stable gas-phase molecules, such as 1,3 diamino propane, in the absence
of plasma. The presence of covalently attached primary amine functionalities was demonstrated by fluorescamine-labeling technique,
further oxallyl chloride-based derivatization, and immobilization of horseradish peroxidase. The existence of specific functionalities
on modified PE surfaces at different derivatization stages, was evidenced by ESCA, ATR-FTIR, and enzyme assay tests.
Received: 16 May 2001/Revised version: 17 July 2001/Accepted: 19 September 2001 |
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Keywords: | |
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