| 相转移催化剂与反应机理的结构适应性研究 |
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| 引用本文： | 郭世豪.相转移催化剂与反应机理的结构适应性研究[J].湖南工业大学学报,2011,25(4):19-22. |
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| 作者姓名： | 郭世豪 |
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| 作者单位： | [1]湖南纺织职工大学成教学院,湖南湘潭411100;[2]湘潭技师学院成教学院,湖南湘潭411100 |
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| 摘 要： | 有机化学反应中,催化剂的选择关系到有机物合成的效率及产物的纯度,为了提高催化剂的研制效率,缩小催化剂的选择范围,对某些季铵盐类相转移催化剂与反应速率、产物组成之间的关系进行了研究。结果表明:适宜的催化剂,其结构往往与反应机理相适应。
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| 关 键 词： | 相转移催化剂 反应机理 结构适应性 |
| 收稿时间： | 5/3/2011 12:00:00 AM |
Study on Structure Adaptability of Phase Transfer Catalysts to Reaction Mechanism |
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| Guo Shihao.Study on Structure Adaptability of Phase Transfer Catalysts to Reaction Mechanism[J].Journal of Hnnnan University of Technology,2011,25(4):19-22. |
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| Authors: | Guo Shihao |
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| Affiliation: | Guo Shihao1,2(1.Department of Adult Education,Hunan Textile Staff & Workers' College,Xiangtan Hunan 411100,China,2.Department of Adult Education,Xiangtan Technician College,China) |
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| Abstract: | The selection of catalysts is of vital importance to the efficiency of organic synthesis and the purity of products in organic reactions. In order to improve the catalyst developing efficiency and reduce the scope of catalyst selection, the relationship between the reaction rate, product composition and phase transfer catalysts of quaternary ammonium is fully studied and the result shows that the structure of the optimum catalysts often adapts to the reaction mechanism. |
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| Keywords: | phase transfer catalyst reaction mechanism structure adaptability |
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