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Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics
作者姓名:Hai-tao Li  Bo-ping Zhang  Qian Zhang  Peng-peng Shang  Gao-lei Zhao
作者单位:Hai-tao Li(School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China ;School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471003, China);Bo-ping Zhang,Qian Zhang,Peng-peng Shang,Gao-lei Zhao(School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China) 
基金项目:the Research Fund for the Doctoral Program of Higher Education of China,the National Basic Research Priorities Program of China,the Program of University-Industry Cooperation Sup-ported by the Ministry of Education and Guangdong Province of China 
摘    要:MgO-modified Li0.06(Na0.5K0.5)0.94NbO3(L6NKN) lead-free piezoelectric ceramics were synthesized by normal sintering at a relatively low temperature of 1000°C.The crystalline phase,microstructure,and electrical properties of the ceramics were investigated with a special emphasis on the influence of MgO content.The addition of MgO effectively improves the sinterability of the L6NKN ceramics.X-ray diffraction analysis indicates that the morphotropic phase boundary(MPB) separating orthorhombic and tetragonal ph...

关 键 词:无铅压电陶瓷  微观结构  电性能  结晶相  MgO含量  机电耦合系数  相对介电常数  无铅压电材料

Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics
Hai-tao Li,Bo-ping Zhang,Qian Zhang,Peng-peng Shang,Gao-lei Zhao.Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics[J].Journal of University of Science and Technology Beijing,2010,17(3):340-346.
Authors:Hai-tao Li  Bo-ping Zhang  Qian Zhang  Peng-peng Shang  Gao-lei Zhao
Affiliation:Hai-tao Li1,2),Bo-ping Zhang1),Qian Zhang1),Peng-peng Shang1),and Gao-lei Zhao1) 1) School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China 2) School of Materials Science and Engineering,Henan University of Science and Technology,Luoyang 471003,China
Abstract:MgO-modified Li0.06(Na0.5K0.5)0.94NbO3 (L6NKN) lead-free piezoelectric ceramics were synthesized by normal sintering at a rela-tively low temperature of 1000℃. The crystalline phase, microstructure, and electrical properties of the ceramics were investigated with a special emphasis on the influence of MgO content. The addition of MgO effectively improves the sinterability of the L6NKN ceramics. X-ray diffraction analysis indicates that the morphotropic phase boundary (MPB) separating orthorhombic and tetragonal phases for the ceramics lies in the range of Mg doping content (x) from 0.3at% to 0.7at%. High electrical properties of the piezoelectric constant (d33=238 pC/N), planar electromechanical coupling coefficient (Kp=41.5%), relative dielectric constant (εr=905), and remanent polarization (Pr=38.3μC/cm2) are obtained from the specimen with x=0.5at%, which suggests mat the Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 (x=0.5at%) ceramic is a promising lead-free piezoelectric material.
Keywords:lead-free piezoelectric ceramics  sinterability  sintering  morphotropic phase boundary
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