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Synthesis of a CrCoAPO-5(AFI) Molecular Sieve and Its Activity in Cyclohexane Oxidation in the Liquid Phase
Authors:Anthony F. Masters  James K. Beattie  Adriana L. Roa
Affiliation:(1) School of Chemistry, The University of Sydney, NSW, 2006, Australia
Abstract:A new CrCoAPO-5 was synthesized under hydrothermal conditions, characterised by X-ray diffraction, scanning electron microscopy, infrared spectroscopy, energy dispersive X-ray analysis, thermogravimetric analysis, electron paramagnetic resonance and nitrogen physisorption. The CrCoAPO-5 showed catalytic activity in the liquid phase oxidation of cyclohexane at 115°C and 1 MPa of oxygen.
Keywords:redox molecular sieves  aluminophosphates  oxidation  cyclohexane
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