Formation of Si diffusion layer on stainless steels and their high temperature corrosion resistance in molten salt |
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| Affiliation: | 1. Institute of Materials, Key Laboratory for Microstructures, Shanghai University, Shanghai 200072, China;2. Shanghai University Xinghua Institute of Special Stainless Steels, Jiangsu 225721, China;3. School of Chemical Engineering, University of Queensland, St Lucia, Brisbane, Queensland 4072, Australia;1. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, 62 Wencui Road, Shenyang City 110016, China;2. Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang City 110819, China;3. Frontier Research Initiative, New Industry Creation Hatchery Center, Tohoku University, 6-6-10, Aoba, Aramaki, Aoba-ku, Sendai 980-8579, Japan;1. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, PR China;2. University of Chinese Academy of Sciences, Beijing, 100049, PR China;3. National Research Centre Kurchatov Institute, Moscow, 123182, Russian Federation |
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| Abstract: | The surface alloying of Si into SUS430 and SUS304 stainless steels was achieved by a pack-cementation method. A high-temperature corrosion test was undertaken under a corrosive ash in a high-temperature gas, which simulated the environment of a waste incinerator. The effect of the surface alloying of Si on the high temperature corrosion resistance of these stainless steels was examined. The result of the corrosion test showed that the corrosion mass loss of the siliconized stainless steel was lower than that of non-treated stainless steel. It was thought that the high temperature corrosion resistance in the corrosive ash containing large amounts of molten salt was improved by the surface alloying of Si. The change in corrosion loss with test time in the corrosive ash was also examined. The corrosion loss of the non-treated stainless steels rapidly increased. On the other hand, the corrosion rate of the siliconized stainless steels was small.It was found from the observation and EPMA analysis of a cross-section of the specimen after the corrosion test that, for the non-treated stainless steels, the metallic elements were dissolved into the molten salt. On the other hand, for the siliconized stainless steels, a scale consisting of silicon oxide was formed on the steels. As a result, the dissolved metallic elements were small.The electrochemical studies indicated that there was an effect of the surface alloying of Si on the hot corrosion resistance of the stainless steels. Hence, the corrosion potentials of the siliconized steels were higher than those of the non-treated steels. The increase in the anodic current densities for the siliconized steels was smaller than that for the non-treated steels. It was thought that the electrochemical corrosion reaction was difficult to occur due to the surface alloying of Si into the stainless steels. |
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