| 对溴苯甲醚合成的研究 |
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| 引用本文： | 邵艳,阎圣刚. 对溴苯甲醚合成的研究[J]. 广东化工, 2006, 33(8): 12-13,22 |
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| 作者姓名： | 邵艳 阎圣刚 |
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| 作者单位： | 大连理工大学,化工学院,辽宁,大连,116024;大连理工大学,化工学院,辽宁,大连,116024 |
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| 摘 要： | 以溴化钠为溴源,氧气为氧化剂进行的苯甲醚的催化氧化溴代反应。确定较佳的工艺条件为:苯甲醚∶溴化钠∶TEMPO(摩尔比)为1∶1.5∶0.003,冰醋酸与水的体积比例为10∶3。以20mmol的苯甲醚在较佳工艺条件下,反应5h,转化率及选择性都达到98.0%以上。
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| 关 键 词： | 苯甲醚 溴化钠 氧气 对溴苯甲醚 |
| 收稿时间： | 2006-05-12 |
| 修稿时间： | 2006-05-12 |
Study on the Synthesis of p-bromo Anisole |
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| Shao Yan,Yan Shenggang. Study on the Synthesis of p-bromo Anisole[J]. Guangdong Chemical Industry, 2006, 33(8): 12-13,22 |
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| Authors: | Shao Yan Yan Shenggang |
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| Affiliation: | School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China |
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| Abstract: | The oxybromination of anisole was investigated with sodium bromide as bromo source and oxygen as oxidant.The optimal reactive conditions were obtained as follow.The mol ratio of anisole,sodium bromide and TEMPO was 1:1.5:0.003,and the volume ratio of acetic acid and water was 10:3.20 mmol of anisole was subjected to the optimal reactive conditions,then reacted for 5 h in vessel,more then 98.0% of conversion and regioselectivity was obtained. |
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| Keywords: | anisole sodium bromide oxygen p-bromo anisole |
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