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镍氢电池用贮氢合金多元化降钴的研究
引用本文:厉海艳,李全安,文九巴,张清,张兴渊.镍氢电池用贮氢合金多元化降钴的研究[J].钢铁研究学报,2007,19(4):62-0.
作者姓名:厉海艳  李全安  文九巴  张清  张兴渊
作者单位:河南科技大学材料科学与工程学院,河南,洛阳,471003
基金项目:河南省杰出青年科学基金 , 河南省高校创新人才培养项目
摘    要: 为了降低贮氢合金中的钴含量,从而降低镍氢电池的价格,在贮氢合金MlNi355Co075Mn04Al03的基础上,依次添加铜、铬、锌及铁元素,得到稀土基多元贮氢合金,并测试和分析了它们的放电容量、循环稳定性以及微观结构。结果表明,采用适量的铜、铬、锌及铁替代钴所得到的低钴贮氢合金仍具有较高的放电容量和较好的循环稳定性,而且其相结构并未改变。

关 键 词:低钴贮氢合金  放电容量  循环稳定性
文章编号:1001-0963(2007)04-0062-03
收稿时间:1900-01-01;
修稿时间:10 30 2006 12:00AM

Low-Cobalt Hydrogen Storage Alloys for Ni-MH Battery
LI Hai-yan,LI Quan-an,WEN Jiu-ba,ZHANG Qing,ZHANG Xing-yuan.Low-Cobalt Hydrogen Storage Alloys for Ni-MH Battery[J].Journal of Iron and Steel Research,2007,19(4):62-0.
Authors:LI Hai-yan  LI Quan-an  WEN Jiu-ba  ZHANG Qing  ZHANG Xing-yuan
Affiliation:School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471003, Henan, China
Abstract:In order to decrease the price of Ni-MH batteries, Cu, Cr, Zn and Fe are added on the basis of MlNi3.55Co0.75 Mn0.4Al0.3, and the low-cobalt hydrogen storage alloys are obtained. And their discharge capacity, cycle stability and their microstructure are determined and analyzed. The results show that low-Co hydrogen storage alloys with high discharge capacity and good cycle stability can be obtained by substituting Cu, Cr, Zn and Fe for Co, and the structure of their phase are same.
Keywords:low-Co hydrogen storage alloy discharge capacity cycle stability
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