Syntheses of sodium 2-(N-alkyl-N-methylamino)ethanephosphates and their physicochemical properties |
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Authors: | Kazuyuki Tsubone Noriko Uchida Hideaki Niwase Keiichi Honda |
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Affiliation: | (1) Cosmetics Laboratory, Kanebo, Ltd., 5-3-28 Kotobukicho, 250 Odawara City, Kanagawa, Japan |
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Abstract: | A series of new amphoteric surfactants, sodium salts of 2-(N-alkyl-N-methylamino)ethanephosphates (alkyl: n-dodecyl, n-tetradecyl
and n-hexadecyl) were prepared by reacting alkylbromides with N-methylaminoethanol, followed by addition of phosphoric acid
groups and neutralization with sodium hydroxide. The structures of these compounds were confirmed by spectroscopy and elemental
analysis. Physical properties such as Krafft point, isoelectric point, critical micelle concentration, occupation area of
molecule at surface, foaming power and the effect of pH on surface activity were evaluated. These surfactants were found to
exhibit zwitterionic characteristics in the pH range from approximately 5 to 9 and demonstrated good surface-active properties
over a wide pH range (pH 4~10). Large occupation areas of the molecule at a surface in comparison with sodium dodecyl sulfate
was noted as a characteristic feature of these surfactants. |
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Keywords: | |
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