Physico-chemical processes occurring inside a degrading two-dimensional anisotropic porous medium

A lumped-parameter kinetic model is applied to simulate the pyrolysis of lignocellulosic particles, exposed to a high temperature environment. Physical processes account for radiative, conductive and convective heat transport, diffusion and convection of volatile species and pressure and velocity variations across a two-dimensional (2-D) , anisotropic, variable property medium. The dynamics of particle degradation are found to be strongly affected by the grain structure of the solid. A comparison is made between the total heat transferred to the virgin solid (conduction minus convection) along and across the grain. Notwithstanding the lower thermal conductivities, because of the concomitant slower convective transport (lower gas permeabilities) , the largest contribution is that across the solid grain. The role played by convective heat transport is successively less important as the particle size is increased. Finally, the 2-D and the widely applied one-dimensional (1-D) predictions are compared.