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石墨/LiFePO_4锂离子电池高温存储后的性能
引用本文:常丽娟,贾元波,万宁,李双杰.石墨/LiFePO_4锂离子电池高温存储后的性能[J].电池,2017,47(1).
作者姓名:常丽娟  贾元波  万宁  李双杰
作者单位:四川省有色冶金研究院有限公司,四川成都,610000
摘    要:将荷电态(SOC)为2%(剩余电量为0.1 Ah)的石墨/LiFePO_4锂离子电池分别在不同温度(25℃、50℃、60℃和70℃)下存储6 h,测试常温/高温荷电保持能力、低温(-20℃)放电和常温1 C循环(2.50~3.65 V)性能。电池的常温/高温荷电保持能力和低温(-20℃)放电性能均随存储温度的升高先增强、后减弱,经60℃存储后,电池的上述性能最优;在常温下1 C循环1 500次后,高温(≥50℃)存储后电池的容量保持率约为88%。

关 键 词:高温存储  荷电保持  固体电解质相界面(SEI)膜  循环性能

Performance of graphite/LiFePO4 Li-ion battery after high temperature storage
CHANG Li-juan,JIA Yuan-bo,WAN Ning,LI Shuang-jie.Performance of graphite/LiFePO4 Li-ion battery after high temperature storage[J].Battery Bimonthly,2017,47(1).
Authors:CHANG Li-juan  JIA Yuan-bo  WAN Ning  LI Shuang-jie
Abstract:The performance of 2 % state-of-charge (SOC) (the remained capacity was 0.1 Ah) for graphite/lithium iron phosphate (LiFePO4) Li-ion battery after stored for 6 h under different temperatures (25 ℃,50 ℃,60 ℃ and 70 ℃) was studied.The normal/high temperature charge retention ability,low temperature(-20 ℃) discharge and normal temperature 1 C cycle(2.50-3.65 V) performance were tested.The normal/high temperature charge retention ability and low temperature (-20 ℃) discharge performance of the batteries increased firstly and then decreased with the increasing of store temperature,when the store temperature was 60 ℃,the optimal value of performance mentioned above was achieved.The discharge capacity retained round 88 % for the stored temperature above 50 ℃ of rated capacity after 1 500 cycles at 1 C.
Keywords:high temperature storage  charge retention  solid electrolyte interphase(SEI) film  cycle performance
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