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EXPERIMENTAL VERIFICATION ON CONVERSION RULES OF STRUCTURAL GROUPS IN HEAVY OIL PROCESSING
Abstract:According to the structural group theory,the chemical composition of petroleum fractions can be classified as structural groups as aromatics,naphthene,olefin and non-hydrocarbon elements etc.Among them,aromatics and naphthene can be further divided into some sub-groups depending on their ring distribution.The chemical reactions in heavy oil processing can be considered as reactions occurred between groups or in the group itself.Based on a large number of data from commercial unit and bench-scale experiments,the rules of chemical structural conversion between feedstock and products in catalytic cracking,delayed coking and hydrocracking were investigated.The feasibility of this theory was verified.Both chemical nature and technological characteristics of these three main processes in heavy oil processing were analyzed.This is favorable to refineries for the selection of rational technical route in processing heavy oil.
Keywords:vacuum gas oil  atmospheric residue  vacuum  residue  constructure  conversion  catalytic cracking  delayed coking  hydrocracking
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