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SnO_2纳米空心球的合成及在锂离子电池正极方面的应用(英文)
引用本文:曹艳霞,王万杰,王经武,陈荣峰.SnO_2纳米空心球的合成及在锂离子电池正极方面的应用(英文)[J].功能材料与器件学报,2009,15(1).
作者姓名:曹艳霞  王万杰  王经武  陈荣峰
作者单位:1. 郑州大学材料科学与工程学院,郑州,450001
2. 河南省科学院,郑州,450002
摘    要:采用锡盐溶液浸渍-煅烧锯末法,制备了SnO2纳米空心球.分别用X射线衍射(XRD)、透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)及恒流充放电技术对产品的结构形态和电化学性质进行了表征.结果表明,SnO2空心球的尺寸在50~120nm之间,壳层厚度约为5nm.在作为锂离子电池正极使用时,初始放电容量为607.7 mAh g-1.

关 键 词:二氧化锡  纳米空心球  锂离子电池

Simple synthesis of SnO_2 hollow nanospheres and application in Lithium-ion battery anodes
CAO Yan-xia,WANG Wan-jie,WANG Jing-wu,CHEN Rong-feng.Simple synthesis of SnO_2 hollow nanospheres and application in Lithium-ion battery anodes[J].Journal of Functional Materials and Devices,2009,15(1).
Authors:CAO Yan-xia  WANG Wan-jie  WANG Jing-wu  CHEN Rong-feng
Affiliation:1.College of Materials Science and Engineering;Zhengzhou University;Zhengzhou 450001;China;2.Henan Academy of Sciences;Zhengzhou 450002;China
Abstract:SnO2 hollow nanospheres were prepared by the simple heat treatment of sawdust impregnated by SnCl4 water solution in alkaline conditions.The crystallographic structure of the sample was determined by X-ray powder diffraction(XRD).The structure and morphology of these hollow SnO2 nanostructures were investigated by transmission electron microscopy(TEM) and high-resolution transmission electron microscopy(HRTEM).The formation mechanism of SnO2 hollow sphere was studied by TEM preliminarily;it indicates that m...
Keywords:SnO2  hollow nanospheres  lithium-ion battery
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