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Combining In‐Situ Organic Modification of Montmorillonite and the Latex Compounding Method to Prepare High‐Performance Rubber‐Montmorillonite Nanocomposites
Authors:Qing‐Xiu Jia  You‐Ping Wu  Yan‐Li Xu  Hui‐Hui Mao  Li‐Qun Zhang
Abstract:Summary: To improve the interfacial interaction in MMT‐SBR nanocomposites, one type of UOAC was introduced to in‐situ modified MMT before latex compounding with SBR. The influence of the UOAC/MMT ratio on the structure and properties of MMT/SBR nanocomposites were carefully studied by XRD, TEM, and mechanical testing. It was found that through the in‐situ organic modification, a rubber‐intercalated structure of MMT was obtained in the nanocomposites, and the amount of rubber‐intercalated structure strongly depended on the UOAC/MMT ratio. The tensile strength of MMT‐SBR nanocomposites was enhanced dramatically from 4 to 18 MPa by in‐situ organic modification of MMT.
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Stress‐strain diagram of SBR/clay nanocomposites.

Keywords:N‐allyl‐N  N‐dimethyl‐octadecylammonium chloride  clay  latex compounding method  nanocomposites  SBR
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