| 负载杂多化合物催化酯类反应研究进展 |
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| 引用本文： | 韩华俊,陈彤,王公应.负载杂多化合物催化酯类反应研究进展[J].工业催化,2006,14(1):1-6. |
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| 作者姓名： | 韩华俊 陈彤 王公应 |
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| 作者单位： | 1.中国科学院成都有机化学研究所，四川 成都 610041;2.中国科学院研究生院，北京 ;100039 |
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| 摘 要： | 综述了杂多化合物催化剂催化酯类反应在国内外的研究和应用情况。杂多化合物由于具有准液相和超强酸性的特征，广泛用于各种酯类反应。杂多酸作为均相催化剂催化酯类反应具有很高的活性和选择性，但存在反应产物和催化剂分离问题。采用杂多酸盐及以活性炭、SiO2、TiO2和MCM-41等负载的杂多化合物多相催化酯类，催化剂不仅具有很高反应活性和选择性，同时易于同产物分离，克服了均相催化的缺点。
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| 关 键 词： | 杂多化合物 负载催化剂 酯类反应 |
| 文章编号： | 1008-0143（2006）01-0001-06 |
| 收稿时间： | 2005-06-30 |
| 修稿时间： | 2005-10-20 |
Recent advances in ester reactions catalyzed by supported heteropoly compounds |
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| HAN Hua-jun,CHEN Tong,WANG Gong-ying.Recent advances in ester reactions catalyzed by supported heteropoly compounds[J].Industrial Catalysis,2006,14(1):1-6. |
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| Authors: | HAN Hua-jun CHEN Tong WANG Gong-ying |
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| Affiliation: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences，Chengdu; 610041，China; 2. Graduate School of Chinese Academy of Sciences, Beijing 10;0039, China |
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| Abstract: | The researches in and application of heteropoly acid,heteropoly salts and heteropoly compounds supported on activated carbon,silica(SiO_2),titania(TiO_2),MCM-41,as the catalysts for ester reaction,were reviewed.Heteropoly compounds,with the properties of quasi-liquid and super acid,has been widely applied to ester reactions.Main problems with application of heteropoly compounds as homogeneous catalyst are separation of the catalyst and reaction products.Supported heteropoly compounds debottleneck the separation problem with homogeneous catalyst,and meanwhile exhibit high activity and selectivity. |
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| Keywords: | heteropoly compound supported catalyst ester reaction |
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