| 二乙酰基四硝基六氮杂异伍兹烷分子和晶体结构 |
| |
| 引用本文： | 冯泽旺,刘翠玲,方涛,赵信歧. 二乙酰基四硝基六氮杂异伍兹烷分子和晶体结构[J]. 火炸药学报, 2001, 24(1): 38-40 |
| |
| 作者姓名： | 冯泽旺 刘翠玲 方涛 赵信歧 |
| |
| 作者单位： | 北京理工大学化工与材料学院, |
| |
| 摘 要： | 测定了制备CL－20的中间体二乙酰基四硝基六氮杂异伍兹烷（DATN）的晶体结构，发现其分子中两个乙酰基处于笼子的一个七元环上，因而可以认为DATN的生成是个高度立体选择性反应。
|
| 关 键 词： | 二乙酰基四硝基六氮杂异伍兹烷 DATN CL-20 晶体结构 中间体 |
| 文章编号： | 1007-7812(2001)01-0038-03 |
Molecular and Crystal Structure of Diacetyltetranitrohexaazaisowurtzitane (DATN) |
| |
| FENG Ze-wang,LIU Cui-ling,FANG Tao,ZHAO Xin-qi. Molecular and Crystal Structure of Diacetyltetranitrohexaazaisowurtzitane (DATN)[J]. Chinese Journal of Explosives & Propellants, 2001, 24(1): 38-40 |
| |
| Authors: | FENG Ze-wang LIU Cui-ling FANG Tao ZHAO Xin-qi |
| |
| Abstract: | Diacetyltetranitrohexaazaisowurtzitane (DATN), the intermediate in the preparation of CL-20, has been determined by single crystal X-ray diffraction. It is a monoclinic, space group P21/n with a=0.8545(2) nm, b=1.3170(3) nm, c=1.5012(3) nm, and α=90°,β=105.66(3)°,γ=90°; Z=4, Dc=1.765g/cm3,R=0.0381, RW=0.0995 for 2857 reflections. Due to the two acetyls lying in a seven-numbered ring of caged structure, the formation of DATN was considered to be a stereo selective reaction. |
| |
| Keywords: | Diacetyltetranitrohexaazaisowurtzitane (DATN) CL 20 Crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
