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Changes of hydrogen storage properties of MgH2 induced by heavy ion irradiation
Authors:J Grbovi? Novakovi?  Lj Matovi?  M Drvend?ija  N Novakovi?  D Rajnovi?  M Šiljegovi?  Z Ka?arevi? Popovi?  S Milovanovi?  N Ivanovi?
Affiliation:1. Laboratory of Material Sciences, Vin?a Institute of Nuclear Sciences, PO Box 522, 11001 Belgrade, Serbia;2. Laboratory for Nuclear and Plasma Physics, Vin?a Institute of Nuclear Sciences, PO Box 522, 11001 Belgrade, Serbia;3. Laboratory of Physics, Vin?a Institute of Nuclear Sciences, PO Box 522, 11001 Belgrade, Serbia;4. Laboratory for Radiation Chemistry and Physics, Vin?a Institute of Nuclear Sciences, PO Box 522, 11001 Belgrade, Serbia;5. Faculty of Technical Sciences, University of Novi Sad, Trg Dositeja Obradovi?a 6, 21000 Novi Sad, Serbia
Abstract:In order to understand the influence of defect zones on desorption behavior of MgH2MgH2, Xe 120 keV ion irradiation of this material has been performed. DSC, SEM measurements, and SRIM calculations have been used to characterize induced modifications and its influence on the hydrogen desorption behavior of MgH2MgH2. We have demonstrated that the near-surface area of MgH2MgH2 plays the crucial role in hydrogen desorption kinetics. DSC analysis provides clear picture of vacancies influence on H diffusion and desorption in MgH2MgH2, and points out that there is possibility to control the thermodynamic parameters by controlled ion bombardment.
Keywords:Hydrogen storage  Magnesium hydride  Ion irradiation  DSC  Monte Carlo simulation
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