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Effective Coke Removal in Methane to Benzene (MTB) Reactionon Mo/HZSM-5 Catalyst by H2 and H2O Co-addition to Methane
Authors:Hongtao Ma  Ryoichi Kojima  Satoshi Kikuchi  Masaru Ichikawa
Affiliation:(1) Catalysis Research Center, Hokkaido University, N-21 W-10, Kita-ku, Sapporo 001-0021, Japan
Abstract:The catalytic dehydro-aromatization reaction over Mo/HZSM-5 catalyst was drastically stabilized by the co-addition of 5.4% H2 and 1.8% H2O to methane feed at 750 °C, 0.3 MPa and methane space velocity of 3000 mL g−1 h−1, suppressing the coke formation effectively, compared with single hydrogen or steam addition.
Keywords:methane dehydro-aromatization  Mo catalyst  H2 addition  H2O addition
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