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硫化锌银精矿富集银的工艺研究
引用本文:顾华祥,贺小塘,袁威,刘琼,范兴祥. 硫化锌银精矿富集银的工艺研究[J]. 贵金属, 2017, 38(1): 69-74. DOI: 10.3969/j.issn.1004-0676.2017.01.014
作者姓名:顾华祥  贺小塘  袁威  刘琼  范兴祥
作者单位:1. 贵研资源(易门)有限公司,昆明,650106;2. 昆明冶金研究院,昆明,650031;3. 贵研铂业股份有限公司,昆明,650106;4. 昆明冶金高等专科学校冶金材料学院,全国再生金属行业稀散及贵金属二次资源循环利用重点实验室,昆明 650033
基金项目:昆明冶金高等专科学校引进人才科研经费资助项目,云南省战略性新兴产业发展专项
摘    要:基于国内外硫化锌矿处理的火、湿法研究进展,对含锌银精矿采用硫酸化焙烧、稀硫酸浸出工艺脱除锌、富集银,考察了焙烧和浸出过程中的主要影响因素。结果表明,硫酸配比为150%,在300℃焙烧90 min,以5%稀硫酸为浸出剂,液固比8:1,搅拌转速200~300 r/min,85℃浸出120 min,最终锌的浸出率可达到98%以上,浸出渣中银含量为7.24%,银被富集7倍。

关 键 词:有色金属冶金  硫化锌  银精矿  预处理  湿法浸出
收稿时间:2016-04-08

Research on the Enrichment of Silver From Silver Zinc Sulfide Concentrate
GU Huaxiang,HE Xiaotang,YUAN Wei,LIU Qiong and FAN Xingxiang. Research on the Enrichment of Silver From Silver Zinc Sulfide Concentrate[J]. Precious Metals, 2017, 38(1): 69-74. DOI: 10.3969/j.issn.1004-0676.2017.01.014
Authors:GU Huaxiang  HE Xiaotang  YUAN Wei  LIU Qiong  FAN Xingxiang
Affiliation:Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 650106, China,Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 650106, China,Kunmin Metallurgical Research Institute, Kunming 650031, China,Sino-platinum Metals Co.Ltd., Kunming 650106, China and Faculty of Metallurgical Material Engineering, Kunming Metallurgy College, Key Lab of Recycling Rare and Precious Metals Secondary Resources, Kunming 650033, China
Abstract:Based on the research progress of pymetallurgical and hydrometallurgical method in the treatment of zinc sulfide ores, a new process was proposed for the concentration of silver from the zinc silver concentrate. The process involves the sulphation roasting and dilute sulphuric acid leaching. The main influencing factors during roasting and leaching were investigated. The results showed that, when the silver zinc sulfide concentrate was roasting at 300℃ for 90 min at 1.5 ratio of sulfuric acid to the concentrate, followed by leaching with 5% sulphuric acid (8:1 liquid-solid ratio) at 85℃ for 120 h at a stirring speed of 200~300 r/min, the leaching rate of zinc exceeded 98% while the silver content in leaching was elevated to 7.24%. The silver was enriched by 7 times.
Keywords:nonferrous metallurgy  zinc sulfide  silver concentrate  concentration  leaching
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