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金银铜合金的相结构分析
引用本文:吴庆伟,柳青,武海军,李强,张杨,王健,孙绍霞,卢绍平.金银铜合金的相结构分析[J].贵金属,2017,38(2):26-29.
作者姓名:吴庆伟  柳青  武海军  李强  张杨  王健  孙绍霞  卢绍平
作者单位:贵研铂业股份有限公司稀贵金属综合利用新技术国家重点实验室,昆明贵金属研究所,昆明 650106
摘    要:对Au-20Ag-10Cu合金进行了X射线衍射、差热分析和扫描电子显微镜观察。结果表明,合金在280~300℃时效发生有序化转变,形成AuCu有序相;在400℃时效发生调幅分解,形成富金固溶体和富银固溶体。计算获得了各物相的晶格常数,测得有序化和调幅分解反应的开始温度分别为245.4℃和321.0℃。

关 键 词:金属材料  金银铜合金  X射线衍射分析  差热分析  相结构
收稿时间:2016/11/3 0:00:00

Phase Structural Analysis of Au-Ag-Cu alloy
WU Qingwei,LIU Qing,WU Haijun,LI Qiang,ZHANG Yang,WANG Jian,SUN Shaoxia and LU Shaoping.Phase Structural Analysis of Au-Ag-Cu alloy[J].Precious Metals,2017,38(2):26-29.
Authors:WU Qingwei  LIU Qing  WU Haijun  LI Qiang  ZHANG Yang  WANG Jian  SUN Shaoxia and LU Shaoping
Affiliation:State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China and State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China
Abstract:The Au-20Ag-10Cu alloy was studied by X-ray diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM). The analytical results showed that the ordering transition took place at the aging temperature from 280℃ to 300℃, forming a AuCu ordered phase. The alloy spinodal decomposition occurred at 400℃, producing a gold-rich solid solution and a sliver-rich solid solution. The lattice constants were calculated. And the starting temperature required for the ordered phase transition and spinodal decomposition were determined to be 245.4℃ and 321.0℃, respectively.
Keywords:metal materials  Au-Ag-Cu alloy  XRD  DTA  phase structure
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