| 新型纳米SO42-/TiO2催化剂制备及催化合成醋酸丁酯 |
| |
| 引用本文： | 章月,蒋平平,董玉明,顾同新,吴洁,郁盛健. 新型纳米SO42-/TiO2催化剂制备及催化合成醋酸丁酯[J]. 工业催化, 2012, 20(12): 63-66. DOI: 10.3969/j.issn.1008-1143.2012.12.013 |
| |
| 作者姓名： | 章月 蒋平平 董玉明 顾同新 吴洁 郁盛健 |
| |
| 作者单位： | 1.江南大学化学与材料工程学院，江苏 无锡 214122; 2.宜兴汉光高新石化有限公司，江苏 无锡 214122 |
| |
| 基金项目： | 国家“十二五”科技支撑计划（2012BAD32B03）资助项目;宜兴科技支撑计划-工业科研经费（SBE201101247）资助项目 |
| |
| 摘 要： | 采用高压水热法合成纳米锐钛矿相TiO2前驱体，通过H2SO4溶液浸渍制备系列新型SO42-/TiO2催化剂,采用XRD、TG-DTG和TEM对其结构和形貌进行表征,并用于催化醋酸与正丁醇的酯化反应，考察H2SO4溶液浓度、浸渍时间和反应时间对酯化率的影响。结果表明,在H2SO4浓度1 mol·L-1、浸渍时间12 h和反应时间180 min条件下，酯化率高达99.2%,催化剂具有优异的催化性能和较佳的重复使用性。
|
| 关 键 词： | 催化化学 固体酸 纳米SO42-/TiO2催化剂 酯化反应 醋酸丁酯 |
Synthesis of butyl acetate catalyzed by novel nanosizedSO42-/TiO2 catalyst |
| |
| ZHANG Yue JIANG Pingping,Dong Yuming,GU Tongxin,WU Jie,YU Shengjian. Synthesis of butyl acetate catalyzed by novel nanosizedSO42-/TiO2 catalyst[J]. Industrial Catalysis, 2012, 20(12): 63-66. DOI: 10.3969/j.issn.1008-1143.2012.12.013 |
| |
| Authors: | ZHANG Yue JIANG Pingping Dong Yuming GU Tongxin WU Jie YU Shengjian |
| |
| Affiliation: | 1.School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China;2.Yixing Han Light High and New Petrochemical Co.,Ltd., Wuxi 214122, Jiangsu, China |
| |
| Abstract: | NanosizedSO42-/TiO2 catalysts were synthesized by impregnating aqueous H2SO4 on anatase TiO2,which was prepared by a novel hydrothermal procedure.The texture properties and morphology ofSO42-/TiO2 catalysts were characterized by XRD,TG-DTG and TEM.Their catalytic activity was evaluated in the esterification of acetic acid with n-butanol. The effects of H2SO4 solution concentration,impregnating time and reaction time on esterification rate were investigated.The results showed that the esterification rate of 99.2% was obtained under the optimum condition as follows: H2SO4 solution concentration 1 mol·L-1,impregnating time 12 h and reaction time 180 min.The obtained catalyst possessed excellent catalytic properties and reusability. |
| |
| Keywords: | catalytic chemistry solid acid nanosized SO42-/TiO2 catalyst esterification butyl acetate |
|
| 点击此处可从《工业催化》浏览原始摘要信息 |
|
点击此处可从《工业催化》下载全文 |
|
