Melt Compounding of Thermoplastic Polyurethanes Incorporating 1D and 2D Carbon Nanofillers |
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Authors: | Dian Yuan Diego Pedrazzoli Greza Pircheraghi |
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Affiliation: | 1. Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, OH, USA;2. Department of Materials Science and Engineering, Sharif University of Technology, Tehran, Iran |
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Abstract: | Thermoplastic polyurethane nanocomposites incorporating carbon nanotubes and graphene nanoplatelets were prepared through melt blending and compression molding, and the compounding process was optimized taking into account the different physical properties of one-dimensional carbon nanotubes and two-dimensional graphene nanoplatelets. Filler dispersion was further improved in the case of carbon nanotubes by noncovalent surface modification using a specific surfactant. The well-dispersed nanofillers favored enhanced phase separation in the thermoplastic polyurethane, leading to a better microstructure, which is able to improve the load transfer and maximize the tensile and viscoelastic properties. |
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Keywords: | Atomic force microscopy carbon nanotubes graphene mechanical properties melt blending morphology scanning electron microscopy thermoplastic polyurethanes |
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