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Synthesis,Characterization of Guar-Containing Polyurethane Films and their Non-enzymatic Caffeic Acid Sensor Applications
Authors:Serap Titretir Duran  Aziz Paşahan  Nurcan Ayhan  Öznur Güngör  Mahmut Alper Cengiz  Süleyman Köytepe
Affiliation:1. Chemistry Department, Faculty of Arts and Science, ?n?nü University, Malatya, Turkeyserap.titretir@inonu.edu.tr;3. Chemistry Department, Faculty of Arts and Science, ?n?nü University, Malatya, Turkey
Abstract:Stable voltammetric sensors were fabricated by dropping the guar-containing polyurethane films on a platinum electrode for the non-enzymatic determination of caffeic acid. The voltammetric responses of PU-G-1% toward caffeic acid have a linear concentration range from 1 to 15?mM with a correlation coefficient of 0.9938. The detection limit of PU-G-1% electrode was approximately 0.25?mM. PU-G-1% sensor showed the good sensitivity, selectivity, high R-value, low detection limit, and high reproducibility toward caffeic acid. Therefore, it is claimed that the polyurethane film containing 1% guar can be used as an excellent selective membrane for caffeic acid detection in the presence of interferent molecules.
Keywords:Caffeic acid  polyurethane films  sensors  voltammetric sensor
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