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锡醇盐的合成研究
引用本文:董占能,吴世华,郭玉忠.锡醇盐的合成研究[J].昆明理工大学学报(理工版),2000,25(6):94-96.
作者姓名:董占能  吴世华  郭玉忠
作者单位:1. 昆明理工大学,生物与化学工程学院,云南,昆明,650093
2. 昆明理工大学,科技处,云南,昆明,650093
摘    要:锡醇盐是溶胶-凝胶法制备ITO薄膜的前驱体。本文采用氨法和醇钠法两种方法研究了用四氯化锡的醇溶液合成锡醇盐,实验结果表明:氨法比醇钠法优越;乙醇、异丙醇、正丁醇反应活性依次降低;锡酸乙酯、锡酸异丙酯、锡酸正丁酯稳定性依次增强。

关 键 词:锡醇盐  ITO薄膜  溶液-凝胶  氨法  醇钠法  合成
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The Studies on the Synthesis of Stannic Alkoxides
DONG Zhan-neng,WU Shi-hua,GUO Yu-zhong.The Studies on the Synthesis of Stannic Alkoxides[J].Journal of Kunming University of Science and Technology(Natural Science Edition),2000,25(6):94-96.
Authors:DONG Zhan-neng  WU Shi-hua  GUO Yu-zhong
Abstract:Stannic a1koxides are the precursor used for preparing of ITO films by the sol gel method. Reactions involving alcoholic: solutions of stanic chloride with either ammonia or sadium alkoxides were investigated. The conclusions of the experiment show: the order of reactivity is EtOH>Pr iOH>Bt nOH; the order of stabi1ity is Sn(OEt) 4
Keywords:stannic alhoxides  ITO film  sol  gel  ammonia method  sodium alkoxide method
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