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复合板用聚氨酯硬泡的研制
引用本文:刘新民,张维丛,许春霞,丰效周,张琼. 复合板用聚氨酯硬泡的研制[J]. 现代塑料加工应用, 2004, 16(1): 3-7
作者姓名:刘新民  张维丛  许春霞  丰效周  张琼
作者单位:1. 青岛科技大学高分子工程材料研究所,266042
2. 青岛第一建筑工程公司,266000
摘    要:以复配的组合多元醇、异氰酸酯、复合催化剂、发泡剂HCFC-141B与H2O、泡沫稳定剂、阴燃剂等为原料,制备了用于建筑隔热板材的聚氨酯硬质泡沫。研究了发泡剂、催化剂、阴燃剂等对发泡工艺和性能的影响。结果表明,以胺、锡类催化剂组成复合催化剂可使发泡工艺及泡沫的物理性能达到使用要求;用水和HCFC-141B组成复合发泡剂可实现优势互补;DMMP(甲基膦酸二甲酸)、TCEP(三氯乙基磷酸酯)与氢氧化铝或三聚氰胺并用作复配阴燃剂可降低阴燃剂的用量,且阴燃效果良好。

关 键 词:聚氨酯硬泡沫 异氰酸酯 催化剂 发泡剂 阻燃剂高分子材料
修稿时间:2003-08-24

STUDY OF THE RIGID POLYURETHANE FOAM FOR SANDWICH PANEL
Liu Xinmin Zhang Weicong Xu Chunxia Feng Xiaozhou Zhang Qiong. STUDY OF THE RIGID POLYURETHANE FOAM FOR SANDWICH PANEL[J]. Modern Plastics Processing and Applications, 2004, 16(1): 3-7
Authors:Liu Xinmin Zhang Weicong Xu Chunxia Feng Xiaozhou Zhang Qiong
Affiliation:Liu Xinmin 1 Zhang Weicong 2 Xu Chunxia 1 Feng Xiaozhou 1 Zhang Qiong 1
Abstract:A rigid polyurethane foam for sandwich panel using as building materials was prepared from complex polyols, PAPI, compound catalyst, HCFC-141b, H 2 O, foam stabilizer ect. The effects of blowing agent, catalyst and flame retardant on process and properties of foam were studied. The results showed that the properties of foam and foaming craft reached the operating requirement with compound catalyst(amine and organ tin). Physical foaming agent(HCFC-141b) and chemical foaming agent (H 2 O) could be complementary each other. The consumption of the flame retardants could be cut down by adopting the compound of DMMP, TCEP and Al(OH) 3 or melamine,and the effect was good.
Keywords:rigid polyurethane foam  catalyst  foaming agent  flame retardant
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