Supuramolecular structure of self-assembly fabricated with novel aromatic polyether on Si-wafers |
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Authors: | Takayanagi Mariko Imai Yoko Yokozawa Tsutomu Tajima Kazuo |
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Affiliation: | Faculty of Engineering, Kanagawa University, Yokohama, JAPAN. |
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Abstract: | A new synthetic polymer of aromatic polyether (APE), having a narrow distribution of molecular weight, formed a specific self-assembly of Langmuir film (L film) on a water surface, which was subjected to surface pressure relaxation when the L film was compressed over 16.5 mN m(-1) at 15 degrees C. This self-assembly was capable of transferring on silicon-wafers as LB films. We found that, because the XRD patterns for fabricated LB films depended on the crystal face of the silicon-wafer used and moreover increased in diffraction intensity with the increasing number of built-up layers in the LB film, the present LB films showed a kind of epitaxy-like phenomenon. We propose the molecular mechanism explaining that the formation of an ionic supuramolecular structure of APE occurs only on a silicon wafer surface. |
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