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沸石分子筛吸附和扩散性质的研究进展
引用本文:夏佳佳,周铭,李天松,王晓宁,刘姝,崔畅.沸石分子筛吸附和扩散性质的研究进展[J].辽宁石油化工大学学报,2018,38(3):35.
作者姓名:夏佳佳  周铭  李天松  王晓宁  刘姝  崔畅
作者单位:(1.辽宁石油化工大学 化学化工与环境学部,辽宁 抚顺 113001;2.辽宁石油化工大学 创新创业学院,辽宁 抚顺 113001;3.辽宁省分析科学研究院,辽宁 沈阳 110015)
基金项目:国家自然科学基金项目(21276120)
摘    要:简述了沸石分子筛的结构组成,介绍了分子筛的性能。综述了物质在沸石分子筛中吸附与扩散的表现,列举了主要分子筛吸附性能与扩散系数的测量方法,介绍了不同类型分子筛的吸附扩散。在目前的研究中,每种测定沸石分子筛吸附性能的方法都有一定的适用条件,每种测定分子筛扩散系数的方法由于测量机理、边界条件与假设条件的不同,所得的扩散系数也有差异,要根据实际实验情况来选择适当的测量方法,不同分子筛适宜吸附的底物也不同,具有不同的应用价值。

关 键 词:分子筛  吸附  扩散  测定方法  
收稿时间:2016-11-21

Research Progress in the Nature of Adsorption and Diffusion on Molecular Sieve
Xia Jiajia,Zhou Ming,Li Tiansong,Wang Xiaoning,Liu Shu,Cui Chang.Research Progress in the Nature of Adsorption and Diffusion on Molecular Sieve[J].Journal of Liaoning University of Petroleum & Chemical Technology,2018,38(3):35.
Authors:Xia Jiajia  Zhou Ming  Li Tiansong  Wang Xiaoning  Liu Shu  Cui Chang
Affiliation:(1.College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun Liaoning 113001,China;2.College of Innovation and Entrepreneurship, Liaoning Shihua University, Fushun Liaoning 113001,China;3.Liaoning Acedemy of Analytic Sciences, Shenyang Liaoning 110015, China)
Abstract:The paper introduces the structure and composition of zeolite molecular sieves, and it elaborates the property of zeolite molecular sieves. In this paper, the performance of the adsorption and diffusion of substances in zeolite molecular sieves is reviewed, and the paper lists the main methods of measuring the performance of molecular sieve's adsorption and diffusion coefficients. It also introduces the adsorption and diffusion of different types of molecular sieves. In the present study, each method of measuring the adsorption performance of zeolite molecular sieves has certain applicable conditions. Due to the difference of measurement mechanism, boundary conditions and assumptions, the diffusion coefficients obtained by different methods are also different. Therefore, the appropriate measurement method will be selected according to the actual experimental situation. As different molecular sieves have different substrates suitable for adsorption, it has different application values.
Keywords:Zeolite  Adsorption  Diffusion  Measurement methods  
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