| 纳米SiO2-氧化石墨烯/聚偏氟乙烯杂化膜的制备及特性 |
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| 引用本文： | 朱振亚,王磊,姜家良,徐亚伟,李青青.纳米SiO2-氧化石墨烯/聚偏氟乙烯杂化膜的制备及特性[J].复合材料学报,2018,35(4):785-792. |
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| 作者姓名： | 朱振亚 王磊 姜家良 徐亚伟 李青青 |
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| 作者单位： | 1. 西安建筑科技大学 环境与市政工程学院 陕西省膜分离重点实验室, 西安 710055;
2. 河北地质大学 水资源与环境学院 河北省水资源可持续利用与开发重点实验室, 石家庄 050031 |
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| 摘 要： | 采用原位水解的方式制备了新型SiO2-氧化石墨烯（GO）纳米杂化颗粒。选择GO、SiO2、SiO2-GO颗粒和聚乙烯吡咯烷酮（PVP）为添加剂，采用浸没沉淀相转化法分别制备了聚偏氟乙烯（PVDF）杂化膜。测定了PVDF杂化膜的纯水通量、膜面接触角、牛血清白蛋白（BSA）截留率和污染恢复率等参数。结果表明，SiO2-GO/PVDF-PVP膜的接触角从78.4°减小到66.02°，膜的亲水性能有所提升。同时，SiO2-GO/PVDF-PVP膜的纯水通量最大（1 018 L/（m2·h）），对BSA的截留率达到81.5%，污染恢复率达到了78.65%以上。新型SiO2-GO纳米杂化颗粒协同PVP添加剂增强了PVDF超滤膜的水通量、污染物截留和抗污染特性等综合性能，为传统PVDF有机膜的改性提供了一种新方法。
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| 关 键 词： | 纳米颗粒 氧化石墨烯 聚偏氟乙烯 杂化膜 抗污染 |
| 收稿时间： | 2017-04-26 |
Preparation and properties of nano SiO2-GO/polyvinylidene fluoride hybrid membrane |
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| ZHU Zhenya,WANG Lei,JIANG Jialiang,XU Yawei,LI Qingqing.Preparation and properties of nano SiO2-GO/polyvinylidene fluoride hybrid membrane[J].Acta Materiae Compositae Sinica,2018,35(4):785-792. |
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| Authors: | ZHU Zhenya WANG Lei JIANG Jialiang XU Yawei LI Qingqing |
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| Affiliation: | 1. Key Laboratory of Membrane Separation of Shaanxi Province, School of Environmental & Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;
2. Key Laboratory of Sustained Development and Utilization of Water Resources, School of Water Resources and Environment, Hebei GEO University, Shijiazhuang 050031, China |
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| Abstract: | SiO2-GO nanohybrid particle was produced via insitu hydrolysis. Through adding SiO2, GO, SiO2-GO nanohybrid particles and polyvinylpyrrolidone (PVP) respectively, the polyvinylidene fluoride(PVDF) hybrid membrane was first prepared through phase inversion by an immersion precipitation technique. The pure water flux, contact angle, fouling recover rate of PVDF hybrid membrane etc were determined. The results show that the contact angles of SiO2-GO/PVDF-PVP hybrid membrane decrease from 78.4° to 66.02°. The rejection rate of bovine serum albumin (BSA) exceeds 81.5% under high water flux (1 018 L/(m2·h)) and the membrane fouling recovery rate is highest (BSA=78.65%). The results show that the synergistic effect of SiO2-GO nanohybrid particles and PVP improve the properties and antifouling ability of hybrid membrane. |
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| Keywords: | nanoparticle graphene oxide poly vinylidene fluoride hybrid membrane antifouling |
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