| 合成酚类抗氧剂1010的新工艺Ⅰ．3，5－二叔丁基－4－羟基苯丙酸甲酯的合成 |
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| 引用本文： | 刘邦孚,汪宝和,刘宗章,郭光远,谈遒. 合成酚类抗氧剂1010的新工艺Ⅰ．3，5－二叔丁基－4－羟基苯丙酸甲酯的合成[J]. 石油化工, 1996, 0(10) |
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| 作者姓名： | 刘邦孚 汪宝和 刘宗章 郭光远 谈遒 |
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| 作者单位： | 天津大学石化技术开发中心 |
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| 摘 要： | 在１５升的不锈钢反应釜中以２，６－二叔丁基苯酚、丙烯酸甲酯为原料，在叔丁醇钾催化剂存在下，对一步法合成抗氧剂１０１０的中间体３，５－二叔丁基－４羟基苯丙酸甲酯的工艺条件进行了研究，优化了反应条件。结果表明，在较佳的条件下，反应的选择性及收率分别超过９８％、９５％。
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| 关 键 词： | 加成反应 选择性 叔丁醇钾 3.5－二叔丁基－4－羟基苯丙酸甲酯 |
Synthesis of Tetrakis [3 (3,5 Di Tert Butyl 4 Hydroxyphenyl) Propionyloxymethyl] Methane by a New Method Ⅰ Studies on the Synthesis of Methyl (3,5 Di Tert Butyl 4 Hydroxyphenyl) Propionate |
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| Liu Bangfu,Wang Baohe,Liu Zongzhang,Guo Guangyuan and Tan Qiu. Synthesis of Tetrakis [3 (3,5 Di Tert Butyl 4 Hydroxyphenyl) Propionyloxymethyl] Methane by a New Method Ⅰ Studies on the Synthesis of Methyl (3,5 Di Tert Butyl 4 Hydroxyphenyl) Propionate[J]. Petrochemical Technology, 1996, 0(10) |
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| Authors: | Liu Bangfu Wang Baohe Liu Zongzhang Guo Guangyuan Tan Qiu |
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| Abstract: | Methyl (3,5 di tert butyl 4 hydroxyphenyl) propionate,an intermediate for the preparation of tetrakis [3 (3,5 di t butyl 4 hydroxyphenyl) propionyloxymethyl] methane by one step method,was synthesized with 2,6 di tert buty phenol and methyl acrylate in the presence of potassium tert butoxide in a 15 liter stainless batch tank reactor.The optimum technological conditions were determined and excellent yield and selectivity were obtained. |
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| Keywords: | addition reaction selectivity potassium tert butoxide methyl (3 5 di tert butyl 4 hydroxyphenyl) propionate |
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