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复合薄膜用交联型水性聚氨酯胶粘剂的研制
引用本文:项尚林,李莹,韩徐.复合薄膜用交联型水性聚氨酯胶粘剂的研制[J].中国胶粘剂,2006,15(1):30-32.
作者姓名:项尚林  李莹  韩徐
作者单位:南京工业大学材料科学与工程学院,江苏省,南京市,210009
摘    要:通过改变羧基(-COOH)含量、异氰酸酯基(-NCO)与羟基(-OH)的摩尔比(R值)、交联剂用量,考察了它们对聚氨酯乳液性能及复合薄膜T型剥离强度的影响。结果表明:粘度随-COOH含量的增大而增大; 随R值的增大先增大后减小,当R值=1.1时体系粘度最大。R值或-COOH含量发生变化,T型剥离强度也跟着发生改变。并且,交联剂能起到提高T型剥离强度的作用,且当交联剂含量为9%最佳。

关 键 词:水性聚氨酯  T型剥离强度  交联剂
文章编号:1004-2849(2006)01-0030-03
收稿时间:2005-07-25
修稿时间:2005年7月25日

Study on modified crosslinking aqueous polyurethane adhesives for film
XIANG Shang-lin,LI Ying,HAN Xu.Study on modified crosslinking aqueous polyurethane adhesives for film[J].China Adhesives,2006,15(1):30-32.
Authors:XIANG Shang-lin  LI Ying  HAN Xu
Affiliation:College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China
Abstract:The effects of the content of carboxyl(COOH),the molar ratio of -NCO and -OH(R value) and the content of crosslinking agent on the properties of aqueous polyurethane (PU)and T peel strength were discussed in this article. It was found that the viscosity of aqueous PU increased with -COOH increasing; with the R value increasing,the viscosity of aqueous PU first increased then minished. When R value was 1.1,the viscosity was biggest,T peel strength was also changed by changing the content of -COOH or R value. Moreover,the cross linker and T peel strength was discussed and it was found that T peel strength increased,and the appropriate content of cross linking agent was 9%.
Keywords:aqueous polyurethane  T peel strength  Crosslinking agent
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