Preparation of ultrafine Fe-Si-C powders in a radio-frequency thermal plasma and their catalytic properties |
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Authors: | T Kameyama K Sakanaka H Arakawa A Motoe T Tsunoda K Fukuda |
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Affiliation: | (1) National Chemical Laboratory for Industry, Higashi 1-1, Tsukuba, 305 Ibaraki, Japan |
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Abstract: | Ultrafine Fe-Si-C powders were prepared from mixed gases of SiH4-CH4-Fe(CO)5 using a newly developed thermal-plasma apparatus with a dual-radio-frequency-coupled-plasma-torch system. The phases of the powders prepared were classified into two groups; one composed of -FeSi2 which was prepared by rapid quenching, while the other was composed of -Fe, Fe3Si, Fe5Si3, FeSi, -SiC and amorphous Si, which were prepared by slow quenching. The diameters of these powders were in the range 5–50 nm. The catalytic activities of these powders for Fischer-Tropsch synthesis were examined. The ultrafine -FeSi2 powder was very active for the selective formation of olefin. On the other hand, powders of -Fe, Fe3Si and Fe5Si3 were low in their selectivity but gave high CO conversion. Relations between the plasma conditions for the preparation of ultrafine Fe-Si-C powders and their catalytic properties are discussed. |
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