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Structural Evolution During Reaction to Form Aluminum Titanate from Sol-Gel Precursors
Authors:Lia A Stanciu  Joanna R Groza  A Jitianu  Maria Zaharescu
Affiliation:  a Chemical Engineering and Materials Science Department, University of California, Davis, California, USA b Institute of Physical Chemistry of the Romanian Academy, Bucharest, Romania
Abstract:Aluminum titanate ceramic materials have been obtained by field-activated sintering of amorphous sol-gel powder precursors. Aluminum titanate formation started at 1000°C. The structural evolution with temperature from the amorphous sol-gel state to the final fully densified ceramic product has been monitored by X-ray diffraction (XRD), Fourier-transform infrared (FTIR), and electron microscopy. The full crystallization of aluminum titanate occurred at 1200°C. The grain size of the specimen densified at 1300°C was between 150 and 500 nm.
Keywords:Aluminum titanate  Aluminum oxide  Titanium oxide  Sintering  Densification  Solid-state reaction  Electric field effects  Ceramics  Sol-gel  Characterization  Infrared spectroscopy  Electron microscopy  Thermal treatment  Electrical conductivity  Kinetics
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