The Formation and Morphology of Nanoparticle Supracrystals |
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Authors: | Danny Haubold Annett Reichhelm Alexander Weiz Lars Borchardt Christoph Ziegler Lydia Bahrig Stefan Kaskel Michael Ruck Alexander Eychmüller |
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Affiliation: | Department of Chemistry and Food Chemistry, Technische Universit?t Dresden, Dresden, Germany |
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Abstract: | Supracrystals are highly symmetrical ordered superstructures built up from nanoparticles (NPs) via self‐assembly. While the NP assembly has been intensively investigated, the formation mechanism is still not understood. To shed some light onto the formation mechanism, one of the most common supracrystal morphologies, the trigonal structures, as a model system is being used to investigate the formation process in solution. To explain the formation of the trigonal structures and determining the size of the supracrystal seeds formed in solution, the concept of substrate‐affected growth is introduced. Furthermore, the influence of the NP concentration on the seed size is shown and our investigations from Ag toward Au are extended. |
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Keywords: | formation mechanism self‐assembly silver nanoparticles substrate‐affected growth supercrystals supracrystals |
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