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电渗析法浓缩低浓度含铜废水
引用本文:瞿广飞,吴淼淼,宁平,郭辉.电渗析法浓缩低浓度含铜废水[J].化工进展,2013,32(10):2497-2500,2517.
作者姓名:瞿广飞  吴淼淼  宁平  郭辉
作者单位:昆明理工大学环境科学与工程学院,云南 昆明 650500
基金项目:教育部重点实验室开放基金,环保部公益项目(201109034)。
摘    要:对低浓度含铜废水(10~50 mg/L)进行了电渗析浓缩实验研究。实验在自制电渗析装置中进行,电渗析反应槽内置交替排列的阴、阳离子交换膜,从而将反应槽分隔成阴、阳极极室、清室和浓室。废水中的铜离子由于电场力的作用透过离子交换膜被富集浓缩。实验分别考察了直流电压、极板间距、通电时间等因素对铜离子去除效率和浓缩倍数的影响,并分析其原因。结果显示,温度20 ℃、电压8 V、pH=7,极板间距360 mm、通电时间1 h时,铜离子去除效率可达90.4%,浓缩倍数为3.5,清室铜离子浓度为1.44 mg/L。

关 键 词:电渗析  浓缩  含铜废水  

Low concentration copper-containing wastewater treatment by electrodialysis concentration
QU Guangfei , WU Miaomiao , NING Ping , GUO Hui.Low concentration copper-containing wastewater treatment by electrodialysis concentration[J].Chemical Industry and Engineering Progress,2013,32(10):2497-2500,2517.
Authors:QU Guangfei  WU Miaomiao  NING Ping  GUO Hui
Affiliation:Faculty of Environmental Science and Engineering,Kunming University of Science and Technology,Kunming 650500,Yunnan,China
Abstract:This research conducted an experiment on low concentration copper-containing wastewater (10 mg/L to 50 mg/L) by electrodialysis concentration in an electrodialysis device. Anion and cation exchange membranes are alternately installed in the electrodialysis reactive tank,which divided the reactor into anodal chamber,cathodal chamber,dilute chamber and concentrated chamber. Driven by electric field force,the copper ions in the wastewater were concentrated before penetrating through the ion exchange membranes. The experiment investigated the influences of DC voltage,electrode spacing,power-on time and other factors on the copper ion removal efficiency and enrichment factor. The results were analyzed in details. The results showed that copper ion removal efficiency can be as high as 90.4% at 20 ℃,8 V,pH=7,360 mm of electrode spacing,1 h of power-on,,and the enrichment factor can be 3.5,and copper ion concentration in the dilute chamber can be as high as 1.44 mg/L.
Keywords:electrodialysis  concentration  copper-containing wastewater
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