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Subsolidus phase relations in the system ZnO–P2O5–MoO3
Authors:Yangping Hong  Dagui Chen  Zhibin Zhan  Xianzhi Chen  Peiwen Lv  Fengbo Yan  Feng Huang  Jingkui Liang  
Affiliation:aKey Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, People's Republic of China
Abstract:The subsolidus phase relations of the ternary system ZnO–P2O5–MoO3 were investigated by means of X-ray diffraction (XRD). Seven binary compounds and eight 3-phase regions were determined, and no ternary compound was found in this system. The phase diagram of pseudo-binary system Zn3(PO4)2–Zn3Mo2O9 was also constructed through XRD and differential thermal analysis (DTA) methods, and the result reveals this system is eutectic system. The eutectic temperature is 904 °C and the corresponding component is 30% Zn3Mo2O9 and 70% Zn3(PO4)2.
Keywords:ZnO–  P2O5  MoO3 system  ZnO crystal growth  Phase diagrams  X-ray diffraction
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