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离子液体在烷基化反应中的应用
引用本文:李艳伟 白雪峰. 离子液体在烷基化反应中的应用[J]. 化学与粘合, 2004, 26(6): 358-361
作者姓名:李艳伟 白雪峰
作者单位:哈尔滨工程大学,化工学院,黑龙江,哈尔滨,150001;黑龙江石油化学研究院,黑龙江,哈尔滨,150040
摘    要:离子液体作为一种环境友好的催化剂和溶剂,受到了人们日益的关注。本文介绍了离子液体独特的性质,重点对离子液体在催化烯烃烷基化制高辛烷值烷基化汽油、苯与烯烃的烷基化制烷基苯,苯与卤代烷烃的烷基化以及萘、酚的烷基化反应中的应用进行综述。在这些反应中,离子液体不仅表现出良好的催化活性和选择性,同时具有产品易分离,催化剂可以循环使用,环境污染小和设备腐蚀不严重等优点。

关 键 词:离子液体  均相催化  烷基化反应
文章编号:1001-0017(2004)06-0358-04

Application of Ionic Liquids in Alkylation Reaction
LI Yan-wei and Bai Xue-feng. Application of Ionic Liquids in Alkylation Reaction[J]. Chemistry and Adhesion, 2004, 26(6): 358-361
Authors:LI Yan-wei and Bai Xue-feng
Affiliation:LI Yan-wei~1 and Bai Xue-feng~2
Abstract:In resent years, the room temperature ionic liquids are being regarded more and more as relatively clean catalysts and solvents. The special properties of ionic liquids are introduced and their application in the fields of production of alkylating gasoline with high octane numbers by olefin alkylation and Friedel-Crafts alkylation of benzene and olefin, benzene and naphthalene, phenol has been reviewed. In these reactions, the ionic liquids have excellent catalytic ability and reactivity and take the advantages such as easy separating from the production process, catalyst reusable and less environmental contamination and equipment corrosion.
Keywords:ionic liquid  homogeneous catalysis  alkylation
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