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Crystal growth and thermal neutron scintillation response of Ce doped KLiYF5
Authors:Yuki Furuya  Hidehiko TanakaNoriaki Kawaguchi  Takayuki YanagidaYuui Yokota  Atsushi YamazakiKenichi Watanabe  Akira Yoshikawa
Affiliation:a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan
b Research & Development Div., Tokuyama. Co. Ltd., ICR-Building, Minamiyoshinari, Aoba-ku, Sendai, Japan
c The Department of Quantum Engineering, Nagoya University, Nagoya 464 8603, Japan
d New Industry Creation Hatchery Center (NICHe), 6-6-10 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8579, Japan
Abstract:K6Li(Y1−xCex)F5 (x = 0.003, 0.02) single crystals were grown from the melt using the precise atmosphere control type Micro-Pulling-Down (μ-PD) method to examine their potential as a new thermal neutron scintillators. The grown crystals were single-phase materials as confirmed by XRD. The crystals demonstrated 40-60% transmittance above 320 nm and Ce3+ 5d-4f luminescence observed around 340 nm when exited by α-ray. The radio luminescence measurements under thermal neutron excitation (252Cf) demonstrated the light yield of 890 (Ph/neutron) and the decay time excited by α-ray exhibited 20 and 259 ns.
Keywords:Ce3+ 5d-4f luminescence  Single crystal growth  Thermal neutron scintillator
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