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| 二氯化苯基膦的合成进展 | |
| 引用本文： | 谢文杰,王鉴,曾群,曲云龙,杨年兴. 二氯化苯基膦的合成进展[J]. 精细化工中间体, 2005, 35(6): 19-21,31 |
| 作者姓名： | 谢文杰 王鉴 曾群 曲云龙 杨年兴 |
| 作者单位： | 1. 大庆石油学院,化学化工学院,黑龙江,大庆,163318 2. 天津大学,化工学院,天津,300000 3. 大庆石化公司,黑龙江,大庆,163318 |
| 摘 要： | 简要的介绍了苯基二氯化磷的用途及发展前景,综述了苯基二氯化磷的合成方法。着重从催化机理和反应历程的角度探讨了三氯化铝催化合成DCPP、离子液体催化合成DCPP、自由基加成反应合成DCPP三类合成反应的过程,并综述了各类反应的进展情况及存在的问题。寻找一条绿色无污染,工艺简单,操作容易,收率高的合成路线,仍然是该领域的热门课题。 |
| 关 键 词： | 二氯化苯基膦 合成机理 中间体 |
| 文章编号： | 1009-9212（2005）06-0019-03 |
| 收稿时间： | 2005-09-21 |
| 修稿时间： | 2005-09-21 |
Development of the Synthesis of Dichlorophenylphosphine |
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| XIE Wen-jie,WANG Jian,ZENG Qun,QUN Yun-long,YANG Nian-xing. Development of the Synthesis of Dichlorophenylphosphine[J]. Fine Chemical Intermediates, 2005, 35(6): 19-21,31 | |
| Authors: | XIE Wen-jie WANG Jian ZENG Qun QUN Yun-long YANG Nian-xing |
| Affiliation: | 1.Chemistry and Chemical Engineering College, Daqing Petraleum Institute, Daqing 163318, China;2.Chemical Engineering College, Tianjin University, Tianj in , China; 3.Daqing Chemical Company SINOPE C, Daqing 163318, China |
| Abstract: | The application and prospect of dichlorophenylphosphine dichloride were briefly introduced, and the synthetic method of dichlorophenylphosphine dichloride was also described. The processes of preparing DCPP through AlCl3 catalytic synthesis,ionic liquid catalytic synthesis,free radical addition reaction synthesis, were discussed mainly in aspect of the mechanism of catalytic reaction, the existing problems and the progress of the study on the reaction were also discussed. Finding a new simple synthetic process which is environment benign and is of high yield as well as easy operation is still a hot issue in this field. |
| Keywords: | dichlorophenylphosphine mechanisms of the reaction intermediate. |
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