| 新拌水泥浆体自由水定量表征方法及作用机理 |
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| 引用本文： | 张雄,赵明,张永娟. 新拌水泥浆体自由水定量表征方法及作用机理[J]. 建筑材料学报, 2016, 19(1): 137-142 |
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| 作者姓名： | 张雄 赵明 张永娟 |
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| 作者单位： | 同济大学材料科学与工程学院,上海201804,同济大学材料科学与工程学院,上海201804,同济大学材料科学与工程学院,上海201804 |
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| 基金项目： | 国家自然科学基金资助项目（51378391） |
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| 摘 要： | 将(新拌)水泥浆体流变性能与水泥颗粒堆积密实度相关联,研究了水泥浆体中自由水的定量表征方法及作用机理.结果表明:利用塑限和液限可以对浆体中自由水分进行分类.第1类自由水,即超过塑限的水分,主要使水泥颗粒产生物理分离.第2类自由水,即超过液限的水分,可使水泥浆体在重力作用下产生流动.减水剂提高水泥浆体流动性不仅是由于其对水泥颗粒具有分散作用,更主要是因为其能降低水泥颗粒对水分的吸附作用,降低水泥颗料弱结合水量,提高浆体自由水量.将水泥浆体流动性能与自由水量进行关联,就能够准确有效地调控水泥浆体的流动性能.
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| 关 键 词： | 自由水 流动性 减水剂 弱结合水 |
| 收稿时间： | 2014-09-10 |
| 修稿时间： | 2014-10-30 |
Quantitative Characterization Methods of Free Water in Fresh Cement Paste and Its Action Mechanism |
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| ZHANG Xiong,ZHAO Ming and ZHANG Yongjuan. Quantitative Characterization Methods of Free Water in Fresh Cement Paste and Its Action Mechanism[J]. Journal of Building Materials, 2016, 19(1): 137-142 |
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| Authors: | ZHANG Xiong ZHAO Ming ZHANG Yongjuan |
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| Affiliation: | School of Materials Science and Engineering, Tongji University, Shanghai 201804, China,School of Materials Science and Engineering, Tongji University, Shanghai 201804, China and School of Materials Science and Engineering, Tongji University, Shanghai 201804, China |
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| Abstract: | The quantitative characterization methods of free water and its action mechanism were studied by relating rheological properties of fresh cement paste to the packing density of cement partials. The results show that free water in cement paste can be classified by the plastic limit and liquid limit. Type 1 free water that is the water exceeding plastic limit can separate cement particles. Type 2 free water that is the water exceeding liquid limit will cause the flow of cement paste under gravity. The improvement of flowability by adding superplasticizer is not only due to the increase of dispersion of cement particles, but also mainly because of lower adsorption force of cement particles to water, lower loose bound water amount of cement particles, and higher free water amount of cement paste. The flowability of cement paste can be accurately and effectively controlled when it is associated with the free water amount. |
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| Keywords: | free water flowability superplasticizer loose bound water |
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