| 甲酸甲酯与三聚甲醛合成乙醇酸甲酯 Ⅲ.羰化反应机理的初步探索 |
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| 引用本文： | 杜碧,林储伟,于作龙. 甲酸甲酯与三聚甲醛合成乙醇酸甲酯 Ⅲ.羰化反应机理的初步探索[J]. 天然气化工, 1998, 0(5) |
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| 作者姓名： | 杜碧 林储伟 于作龙 |
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| 作者单位： | 中国科学院成都有机化学研究所 |
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| 基金项目： | 鲁南水煤浆气化与煤化工国家工程中心资助,国家自然科学基金 |
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| 摘 要： | 提出并初步证实了甲酸甲酯与三聚甲醛合成乙醇酸甲酯反应中的羰化反应机理，具体为：（１）甲酸甲酯分解产生ＣＯ和甲醇；（２）甲醛羰化、甲缩醛羰化形成乙醇酸甲酯和甲氧基乙酸甲酯；（３）产物间部分聚合反应。
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| 关 键 词： | 甲酸甲酯；三聚甲醛；乙醇酸甲酯；反应机理 |
Synthesis of methyl glycolate by coupling methyl formate with trioxane Ⅲ.Exploration of carbonyl reaction mechanism |
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| Du Bilin,Chu Wei,Yu Zuolong. Synthesis of methyl glycolate by coupling methyl formate with trioxane Ⅲ.Exploration of carbonyl reaction mechanism[J]. Natural Gas Chemical Industry, 1998, 0(5) |
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| Authors: | Du Bilin Chu Wei Yu Zuolong |
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| Abstract: | The reaction mechanism is proposed and vertified for synthesis of methyl glycolate via coupling methyl formate with trioxane, which involves decomposition of methyl formate into carbon monoxide and methanol, trioxane carbonylation and methylal carbonylation to give methyl glycolate and methyl methoxyacetate, and polymerization of part of the products. |
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| Keywords: | methyl formate trioxane methyl glycolate reaction mechanism |
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