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压裂返排液中有机物含量的表征方法探讨
引用本文:袁宏林,王海蒙,刘 昂,薛 晨,王新强.压裂返排液中有机物含量的表征方法探讨[J].油田化学,2013,30(1):133-136.
作者姓名:袁宏林  王海蒙  刘 昂  薛 晨  王新强
作者单位:1. 西安建筑科技大学环境与市政工程学院,陕西西安,710055
2. 中国石油长庆油田分公司第二采气厂,陕西榆林,719000
3. 延长油田股份有限公司安全环保质监部,陕西延安,716000
4. 西安石油大学化学化工学院,陕西西安,710065
基金项目:陕西省自然科学基金项目“采油水处理和地下水保护”(项目编号2011JY001);陕西省教育厅专项科研计划项目“陕北气田采气污水中甲醇在环境中的降解规律及影响研究”(项目编号2010JK783);陕西省科学技术研究发展计划项目“等离子体处理陕北采气污水中有机污染物技术研究”(项目编号2011K17-03-11)
摘    要:针对压裂返排液成分复杂,处理过程中有机物含量难以表征这一特点,以压裂返排液中主剂羟丙基瓜尔胶为研究对象,分别采用测定体系化学耗氧量(COD)和总有机碳(TOC)方法研究了有机物含量、氯离子含量和氧化处理对其含量表征的影响。结果表明:COD表征压裂液返排液的有机物含量有较大局限性,TOC比COD更适合表征羟丙基瓜尔胶溶液中有机物的含量。

关 键 词:有机物表征  COD  TOC  羟丙基瓜尔胶

Discussion for the Characterization Method of Organic Matter Content in Fracturing Fluid
YUAN Hong-Lin,WANG Hai-Meng,LIU Ang,XUE Chen,WANG Xin-Qiang.Discussion for the Characterization Method of Organic Matter Content in Fracturing Fluid[J].Oilfield Chemistry,2013,30(1):133-136.
Authors:YUAN Hong-Lin  WANG Hai-Meng  LIU Ang  XUE Chen  WANG Xin-Qiang
Affiliation:1.School of Environmental and Municipal Engineering,Xi’an University of Architecture and Technology,Xi’an,Shaanxi 710055,P R of China;2.The 2nd Gas Production Plant,Chongqing Oilfield Branch Company,PetroChina,Yulin,Shaanxi 719000,P R of China;3.Safety Environmental Protection Qualitative Inspect Department,Yanchang Oilfield Limited Company,Yanan,Shaanxi 717200,P R of China;4.College of Chemical Engineering,Xi’an Shiyou University,Xi’an,Shaanxi 710065,P R of China)
Abstract:The composition of the flowback fluid was complex and it is difficult to characterize the organic matter content. The hydroxypropyl guar gum, which is the main components of fracturing fluid was chosen as the research project, the effect of the content of organic matter and cholrine ion, oxidation treatment on the identification of the organic matter content of fracturing liquid were investigated by measurement of chemical oxygen demand(COD) and total organic carbon (TOC), respectively. The results showed that there was larger limitation when using COD method to characterize liquid organic matter content of fracturing fluid, while TOC was more suitable to charaterize the content of the organic matter of hydroxypropyl guar gum solution.
Keywords:organic characterization  chemical oxygen demand  total organic carbon  hydroxypropyl guar gum
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