Direct incorporation of vanadium into three-dimensional KIT-6: 2. Reactivity test for styrene oxidation |
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Authors: | Balasamy Rabindran Jermy Sang-Yun Kim Kanattukara Vijayan Bineesh Manickam Selvaraj Seung-Kug Song Jong-Woo Ryu Dae-Won Park |
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Affiliation: | (1) Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia |
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Abstract: | The direct incorporation of vanadium into the three-dimensional (3-D) cubic Ia3d mesostructure designated as V-KIT-6 was prepared, and the material obtained therein showed a very high specific surface area of ∼1,000 m2/g with tunable pore diameters in a narrow distribution of sizes, ∼5.7 to 6.0 nm. The coordination and nature of the V sites in V-KIT-6 were characterized by 51V-spin-echo NMR analysis. It shows that after calcination, the V4+ species are totally oxidized to the V5+ state with 4- and 6-coordinated V-O environments in a highly dispersed state with much less crystalline V2O5 formation. The calcined V-KIT-6 materials showed excellent catalytic activity in the direct oxidation of styrene using tert-butyl hydroperoxide (TBHP) as an oxidant. |
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