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松散煤体低温氧化放热强度的测定和计算
引用本文:徐精彩,文虎,葛岭梅,张辛亥,邓军.松散煤体低温氧化放热强度的测定和计算[J].煤炭学报,2000,25(4):387-390.
作者姓名:徐精彩  文虎  葛岭梅  张辛亥  邓军
作者单位:西安科技学院,采矿系,陕西,西安,710054
基金项目:国家自然科学基金资助项目!( 5 99740 2 0 )
摘    要:根据煤低温自然火实验台测定的温度场变化和传热理论,推导出计算不同温度松散煤体低温氧化放热强度的热平衡法;由实验测定的气体浓度变化量,推算出不同温度时煤氧复合的耗氧速率、CO和CO2产生率;结合煤氧复合过程的键能量变化量,得出低温氧化放热强度的键艰算法,确定其上限和下限,为煤自燃特性的定量分析及自然发火预测提供了理论依据。

关 键 词:煤自燃  氧化放热强度  键能估算法  松散煤体
修稿时间:1999-12-01

Determination and calculation of oxidation heat liberation intensity of loose coal at low temperature stage
XU Jing-cai,WEN Hu,GE Ling-mei,ZHANG Xin-hai,DENG Jun.Determination and calculation of oxidation heat liberation intensity of loose coal at low temperature stage[J].Journal of China Coal Society,2000,25(4):387-390.
Authors:XU Jing-cai  WEN Hu  GE Ling-mei  ZHANG Xin-hai  DENG Jun
Abstract:According to heat transfer theory and the change of temperature field determined through experiment of coal self ignite at low temperature stage, thermal equilibrium method is developed to calculate oxidation heat liberation intensity of loose coal at different low temperature stage. The speed of coal oxidation consuming O 2, creating CO and CO 2 is calculated by the concentration change of gas determined by experiment. Connected bond energy change in coal and oxygen combination process, bond energy estimation method is gained to calculate upper and lower limit of oxidation heat liberation intensity of loose coal at different low temperature stage. It offers a theoretic criterion for quantitatively analyzing characteristic of coal self ignite and forecasting coal spontaneous combustion.
Keywords:coal self  ignite  oxidation heat liberation intensity of coal  bond  energy estimation method  
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