Non-polymeric binders for ceramic powders: utilization of neutral and ionic species derived from decaborane(14) |
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| Authors: | William S. Rees Jr Dietmar Seyferth |
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| Affiliation: | (1) Department of Chemistry, Massachusetts Institute of Technology, 02139 Cambridge, Massachusetts, USA |
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| Abstract: | The pyrolytic conversion of bis-Lewis base adducts of decaborane(14), L·B10H12·L (L=neutral monophosphine) and phosphonium salts of the [B10H10]2– anion (e.g. [Ph4P+]2, etc.), to ceramic materials has been studied. All species examined served as binders for a variety of non-oxide refractory ceramic powders (e.g. B4C, BN, BP, B13P2, SiC, Si3N4, B, C, AIN). |
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