| 几种新型吡啶卟啉季铵盐化合物的合成 |
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| 引用本文： | 高焕君,韩士田,刘彦钦.几种新型吡啶卟啉季铵盐化合物的合成[J].化学试剂,2005,27(12):757-758,760. |
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| 作者姓名： | 高焕君 韩士田 刘彦钦 |
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| 作者单位： | 河北师范大学,化学学院,河北,石家庄,050091 |
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| 基金项目： | 河北省自然科学基金资助项目（203147）. |
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| 摘 要： | 采用了以吡咯和吡啶甲醛为原料,二甲苯为溶剂,水杨酸为催化剂的新反应体系合成了meso-四（4-吡啶基）卟啉.再与不同链长的溴代烃作用,合成了3种新型吡啶卟啉季铵盐化合物.其结构通过元素分析、紫外可见光谱、红外光谱、核磁共振谱和质谱确证.
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| 关 键 词： | 吡啶卟啉 季铵盐 合成 |
| 文章编号： | 0258-3283（2005）12-0757-02 |
| 收稿时间： | 2005-03-22 |
| 修稿时间： | 2005-03-22 |
Synthesis of some new types of pyridyl- porphyrin quaternary ammonium salts |
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| GAO Huan-jun,HAN Shi-tian,LIU Yan-qin.Synthesis of some new types of pyridyl- porphyrin quaternary ammonium salts[J].Chemical Reagents,2005,27(12):757-758,760. |
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| Authors: | GAO Huan-jun HAN Shi-tian LIU Yan-qin |
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| Affiliation: | College of Chemistry, Hebei Normal University, Shijiazhuang 050091, China |
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| Abstract: | Meso-tetra(4-pyridyl)porphyrin was synthesized by codensation of pyrrole with 4-pyridylaldehyde in refluxing xylene in the presence of salicylic acid.Based on this,three new types of pyridyl-porphyrin quaternary ammonium salts with alkyl bromide were synthesized.Their structures were demonstrated by elemental analysis,IR, 1HNMR ,MS and UV-Vis spectra. |
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| Keywords: | meso-tetra(4-pyridyl)porphyrin quaternary ammonium salts synthesis |
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