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New High‐Nitrogen Materials Based on Nitroguanyl‐Tetrazines: Explosive Properties,Thermal Decomposition and Combustion Studies
Authors:David&#x;E Chavez  Bryce&#x;C Tappan  Michael&#x;A Hiskey  Steve&#x;F Son  Herbert Harry  Dennis Montoya  Stephanie Hagelberg
Abstract:This paper describes the explosive sensitivity and performance properties of two novel high‐nitrogen materials, 3,6‐bis‐nitroguanyl‐1,2,4,5‐tetrazine ( 1 , (NQ2Tz)) and its corresponding bis‐triaminoguanidinium salt ( 2 , (TAG)2(NQ)2Tz)). These materials exhibit very low pressure dependence in burning rate. Flash pyrolysis/FTIR spectroscopy was performed, and insight into this interesting burning behavior was obtained. Our studies indicate that 1 and 2 exhibit highly promising energetic materials properties.
Keywords:Explosive Sensitivity  Thermal Decomposition  Nitroguanyl‐Tetrazines
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