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新型合成乙苯烷基化催化剂的工业应用
引用本文:谷长洪,邱宝军,李红娟. 新型合成乙苯烷基化催化剂的工业应用[J]. 工业催化, 2013, 21(11): 65-68. DOI: 10.3969/j.issn.1008-1143.2013.11.015
作者姓名:谷长洪  邱宝军  李红娟
作者单位:1.中国石油吉林石化公司化肥厂,吉林 吉林 132021;2.中国石油吉林石化公司丙烯腈厂,吉林 吉林 132021
摘    要:介绍一种新型合成乙苯烷基化催化剂EBZ-800在某大型工业化装置上的工业应用情况,研究不同反应条件下的催化性能。通过对反应条件的研究与优化,得出催化剂在温度200 ℃和苯与乙烯质量比7.5∶1的条件下,目标产品乙苯收率达到87.5%,高于其他工业化催化剂3.5%。研究催化剂在原料苯中不同水含量条件下的反应性能,结果表明,水含量小于100×10-6时,催化剂活性最高。装置在优化条件下运行,易操作控制,节约能耗2.5%,经济效益良好。

关 键 词:有机化学工程  乙苯  烷基化  苯乙烯  催化剂EBZ-800  

Commercial application of a novel alkylation catalyst for the synthesis of ethylbenzene
GU Changhong,QIU Baojun,.,LI Hongjuan. Commercial application of a novel alkylation catalyst for the synthesis of ethylbenzene[J]. Industrial Catalysis, 2013, 21(11): 65-68. DOI: 10.3969/j.issn.1008-1143.2013.11.015
Authors:GU Changhong  QIU Baojun  .  LI Hongjuan
Affiliation:1.Fertilizer Plant of Jilin Petrochemical Company, PetroChina, Jilin 132021, Jilin, China; 2.Acrylonitrile Plant of Jilin Petrochemical Company, PetroChina, Jilin 132021, Jilin, China
Abstract:The commercial application of a novel alkylation catalyst EBZ-800 for the synthesis of ethyl- benzene was introduced, and the performance of catalyst EBZ-800 under different reaction conditions was investigated. The results indicated that under the optimal condition of reaction temperature 200 ℃, mass ratio of benzene/ethylene = 7.5 : 1, ethylbenzene yield over catalyst EBZ-800 was 87.5%, which was 3.5% more than that over other commercial catalyst. When water content was less than 100 x 10-6 ,the catalyst possessed the highest activity. The plant was easy to operate, and its energy consumption was reduced 2.5 %. The better economical benefit was attained under the mild reaction condition.
Keywords:organic chemical engineering  ethylbenzene  alkylation  styrene  catalyst EBZ-800
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