Abstract: | A high-resolution electron-microscopic study of sodium β′″-alumina, a polytype of the more-widely-studied sodium β- and β″-alumina, has been undertaken using the 600 kV instrument at Cambridge University. Images revealed the loss of sodium-containing planes, which had caused crystals to collapse and shear into defect layers. A model for the structure of these defects is proposed, based on the use of computed images and by comparison with high-resolution images of silver β″-alumina. |