HDS reactivities of dibenzothiophenic compounds in a LC-finer LGO and H2S/NH3 inhibition effect

The hydrodesulfurization (HDS) reactivities and the inhibition effects of H₂S and NH₃ were experimentally investigated for 11 difficult-to-remove sulfur compounds contained in LC-finer light gas oil using a commercial NiMo/Al₂O₃ hydrotreating catalyst. Among these sulfur compounds, 4-MDBT was the most reactive while 4,6-DMDBT was the least reactive. It was found that the presence of methyl groups away from the sulfur atom slightly enhanced the HDS reactivities of the methyl substituted DBTs. The observed low reactivity of 4,6-DMDBT was mainly caused by the steric hindrance of the two methyls at the 4 and 6 positions. Both H₂S and NH₃ significantly inhibited the HDS reaction rates for all 11 sulfur species of interest, while 4,6-DMDBT was one of the most inhibited species. At the same concentration (1.0 vol%), H₂S showed a stronger inhibition effect than NH₃. Measurable catalyst deactivation was observed in the course of the experiment that had a relatively even effect on the HDS of all reactants investigated in this study.